Mechanistic Studies of a Reaction Promoted by the [YLi 3 {tris(binaphthoxide)}] Complex: Are Three 1,1′‐Bi‐2‐naphthol Units in a Rare‐Earth–Alkali‐Metal Heterobimetallic Complex Necessary? | Zendy

Yamagiwa Noriyuki | Zendy; Matsunaga Shigeki | Zendy; Shibasaki Masakatsu | Zendy

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Mechanistic Studies of a Reaction Promoted by the [YLi 3 {tris(binaphthoxide)}] Complex: Are Three 1,1′‐Bi‐2‐naphthol Units in a Rare‐Earth–Alkali‐Metal Heterobimetallic Complex Necessary?

Author(s) -

Yamagiwa Noriyuki,

Matsunaga Shigeki,

Shibasaki Masakatsu

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200454202

Subject(s) - tris , amine gas treating , catalysis , alkali metal , chemistry , rare earth , metal , chalcone , content (measure theory) , combinatorial chemistry , stereochemistry , organic chemistry , mineralogy , mathematics , biochemistry , mathematical analysis

The power of three : Mechanistic studies based on the kinetic profiles of the catalytic asymmetric 1,4‐addition of an amine to chalcone revealed that all three binol ligands of the [YLi 3 {tris(binaphthoxide)}] complex 1 are involved in the active species of the Y–Li heterobimetallic catalyst.

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