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Crystal Structure of a Dewar Benzene Derivative Formed from Fluoro(triisopropylsilyl)acetylene
Author(s) -
Hanamoto Takeshi,
Koga Yukinori,
Kawanami Toshio,
Furuno Hiroshi,
Inanaga Junji
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200454174
Subject(s) - acetylene , benzene , derivative (finance) , chemistry , crystal structure , crystallography , photochemistry , medicinal chemistry , organic chemistry , business , finance
Spontaneous trimerization of fluoro(triisopropylsilyl)acetylene, prepared from 1,1‐difluoroethylene in one step, gives the corresponding fluorinated Dewar benzene derivative, whose structure was determined by X‐ray diffraction (see picture).