Cycloisomerization Promoted by the Combination of a Ruthenium–Carbene Catalyst and Trimethylsilyl Vinyl Ether, and its Application in The Synthesis of Heterocyclic Compounds: 3‐Methylene‐2,3‐dihydroindoles and 3‐Methylene‐2,3‐dihydrobenzofurans | Zendy

Terada Yukiyoshi | Zendy; Arisawa Mitsuhiro | Zendy; Nishida Atsushi | Zendy

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Cycloisomerization Promoted by the Combination of a Ruthenium–Carbene Catalyst and Trimethylsilyl Vinyl Ether, and its Application in The Synthesis of Heterocyclic Compounds: 3‐Methylene‐2,3‐dihydroindoles and 3‐Methylene‐2,3‐dihydrobenzofurans

Author(s) -

Terada Yukiyoshi,

Arisawa Mitsuhiro,

Nishida Atsushi

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200454157

Subject(s) - cycloisomerization , ruthenium , carbene , methylene , trimethylsilyl , chemistry , catalysis , ether , organic chemistry , medicinal chemistry , vinyl ether , copolymer , polymer

Substituted N and O heterocycles have been synthesized by the cycloisomerization of dienes using a ruthenium‐carbene catalyst. The products obtained with and without trimethylsilyl vinyl ether differ (see scheme, Cy=cyclohexyl, Mes=2,4,6‐trimethylphenyl, Ts= p ‐toluenesulfonyl).

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