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Fully Metalated Silsesquioxanes: Building Blocks for the Construction of Catalyst Models
Author(s) -
Lorenz Volker,
Gießmann Stephan,
Gun'ko Yurii K.,
Fischer Axel K.,
Gilje John W.,
Edelmann Frank T.
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200454094
Subject(s) - silsesquioxane , catalysis , alkali metal , chemistry , computer science , materials science , organic chemistry , polymer
Versatile building blocks for the construction of molecular models for heterogeneous catalysts are readily available in high yields in the form of fully metalated silsesquioxane derivatives, such as dimeric 1 , by using alkali‐metal silylamides as deprotonating agents.