Selecting Different Complexes from a Dynamic Combinatorial Library of Coordination Compounds | Zendy

Albrecht Markus | Zendy; Janser Ingo | Zendy; Runsink Jan | Zendy; Raabe Gerhard | Zendy; Weis Patrick | Zendy; Fröhlich Roland | Zendy

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Selecting Different Complexes from a Dynamic Combinatorial Library of Coordination Compounds

Author(s) -

Albrecht Markus,

Janser Ingo,

Runsink Jan,

Raabe Gerhard,

Weis Patrick,

Fröhlich Roland

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200453975

Subject(s) - catechol , crystallization , ligand (biochemistry) , coordination complex , tris , lithium (medication) , chemistry , carbonate , potassium carbonate , combinatorial chemistry , solvent , potassium , metal , organic chemistry , biochemistry , biology , receptor , endocrinology

A choice selection : A dynamic combinatorial library of oligonuclear coordination compounds is formed from a flexible tris(catechol) ligand with titanium( IV ) ions in the presence of lithium carbonate or potassium carbonate. A trinuclear complex ( 1 ) can be isolated by crystallization from DMF. In contrast, well‐defined mononuclear ( 2 ) compounds are obtained by addition of Na + as a template, and tetranuclear compounds ( 3 ) are isolated by changing the solvent to DMSO.

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