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The Trifluoromethoxy Sulfuryl Radical, CF 3 OSO 2 .
Author(s) -
von Ahsen Stefan,
Francisco Joseph S.
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200453925
Subject(s) - radical , matrix (chemical analysis) , chemistry , content (measure theory) , computational chemistry , mathematics , organic chemistry , chromatography , mathematical analysis
A radical with great implications : Matrix‐isolated CF 3 O radicals interact with SO 2 yielding CF 3 OSO 2 . (see picture) when the matrix is annealed at 35 K. The new radical was characterized spectroscopically and studied by DFT calculations. CF 3 OSO 2 . may have significant impact on atmospheric processes.
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