Expanding and Shrinking Porous Modulation Based on Pillared‐Layer Coordination Polymers Showing Selective Guest Adsorption | Zendy

Maji Tapas Kumar | Zendy; Uemura Kazuhiro | Zendy; Chang HoChol | Zendy; Matsuda Ryotaro | Zendy; Kitagawa Susumu | Zendy

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Expanding and Shrinking Porous Modulation Based on Pillared‐Layer Coordination Polymers Showing Selective Guest Adsorption

Author(s) -

Maji Tapas Kumar,

Uemura Kazuhiro,

Chang HoChol,

Matsuda Ryotaro,

Kitagawa Susumu

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200453923

Subject(s) - microporous material , pillar , adsorption , thermal stability , porosity , polymer , coordination polymer , chemical engineering , crystallography , molecule , materials science , porous medium , chemistry , nanotechnology , organic chemistry , engineering , mechanical engineering

Rationally designed and synthesized , two novel pillar‐layered 3D microporous frameworks {[Cd(pzdc)(azpy)]⋅2 H 2 O} n ( 1 , left) and {[Cd(pzdc)(bpee)]⋅1.5 H 2 O} n ( 2 , right) have high thermal stability and highly selective adsorption properties. Removal of guest water molecules results in the expansion of 1 but the contraction of 2 .

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