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Visualization of Local Valence Structures in Quasi‐One‐Dimensional Halogen‐Bridged Complexes [Ni 1− x Pd x (chxn) 2 Br]Br 2 by STM
Author(s) -
Takaishi Shinya,
Miyasaka Hitoshi,
Sugiura Kenichi,
Yamashita Masahiro,
Matsuzaki Hiroyuki,
Kishida Hideo,
Okamoto Hiroshi,
Tanaka Hisaaki,
Marumoto Kazuhiro,
Ito Hiroshi,
Kuroda Shinichi,
Takami Tomohide
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200453905
Subject(s) - valence (chemistry) , halogen , bromine , crystallography , visualization , physics , condensed matter physics , metal , chemistry , materials science , molecular physics , atomic physics , quantum mechanics , computer science , data mining , alkyl , organic chemistry
State secrets: Mott–Hubbard and charge‐density‐wave states have been observed in the quasi‐1D bromine‐bridged Ni and Pd complexes [M(chxn) 2 Br]Br 2 , respectively, using STM (see image for the Ni complex, the arrow denotes the direction of the chain). The spin soliton was also visualized in real space in the Ni‐Pd mixed‐metal complexes for the first time. chxn: (1 R ,2 R )‐diaminocyclohexane.