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The Polyhedral Gallium Subhalide [Ga 24 Br 22 ]⋅10 THF: The First Step on the Path to a New Modification of Gallium?
Author(s) -
Duan Taike,
Baum Elke,
Burgert Ralf,
Schnöckel Hansgeorg
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200453786
Subject(s) - gallium , boron , path (computing) , topology (electrical circuits) , chemistry , shell (structure) , crystallography , nanotechnology , materials science , organic chemistry , combinatorics , computer science , mathematics , programming language , composite material
Shell suits : Two shells of Ga 12 icosahedra characterize the arrangement of 24 gallium atoms in the title compound (see structure). The structure indicates connectivity possibilities of Ga 12 units that are analogous to the topology of the α‐boron modification.