Regio‐ and Stereoselective Tether‐Directed Remote Functionalization of C 60  with Derivatives of the Tröger Base | Zendy

Sergeyev Sergey | Zendy; Diederich François | Zendy

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Regio‐ and Stereoselective Tether‐Directed Remote Functionalization of C 60 with Derivatives of the Tröger Base

Author(s) -

Sergeyev Sergey,

Diederich François

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200453743

Subject(s) - stereoselectivity , adduct , enantiomer , surface modification , base (topology) , stereochemistry , chemistry , molecule , regioselectivity , organic chemistry , catalysis , mathematics , mathematical analysis

Bringing two fascinating molecules together : Bismalonate derivatives of the Tröger base were used in the high‐yielding regio‐ and diastereoselective preparation of bisadducts of C 60 with trans ‐1, trans ‐2, and trans ‐4 addition patterns (e.g. see structure). Moreover, both enantiomers of the inherently chiral trans ‐2 adduct were prepared from enantiomerically pure tethers.

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