Porous Organic–Inorganic Assemblies Constructed from Keggin Polyoxometalate Anions and Calix[4]arene–Na +  Complexes: Structures and Guest‐Sorption Profiles | Zendy

Ishii Yusuke | Zendy; Takenaka Yasumasa | Zendy; Konishi Katsuaki | Zendy

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Porous Organic–Inorganic Assemblies Constructed from Keggin Polyoxometalate Anions and Calix[4]arene–Na + Complexes: Structures and Guest‐Sorption Profiles

Author(s) -

Ishii Yusuke,

Takenaka Yasumasa,

Konishi Katsuaki

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200453693

Subject(s) - polyoxometalate , sorption , calixarene , chemistry , inorganic chemistry , porosity , keggin structure , materials science , polymer chemistry , crystallography , organic chemistry , ion , adsorption , molecule , catalysis

Amphiphilic pore walls facilitate reversible sorption of short‐chain alcohols by the 1D microporous organic–inorganic hybrid [ 1 ‐Na] 3 [PW 12 O 40 ] assembled from calix[4]arene–Na + complex 1 ‐Na + (R 1 =R 2 =H) and the polyoxotungstate anion [PW 12 O 40 ] 3− . The analogous assembly formed with 2 ‐Na + (R 1 = t Bu, R 2 =CH 2 CO 2 Et) has a 3D microporous architecture.

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