Dithiocarbamate Group Transfer Cyclization Reactions of Carbamoyl Radicals under “Tin‐Free” Conditions | Zendy

Grainger Richard S. | Zendy; Innocenti Paolo | Zendy

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Dithiocarbamate Group Transfer Cyclization Reactions of Carbamoyl Radicals under “Tin‐Free” Conditions

Author(s) -

Grainger Richard S.,

Innocenti Paolo

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200453600

Subject(s) - radical , chemistry , dithiocarbamate , tin , group (periodic table) , free radical reaction , nitrogen , organic chemistry , combinatorial chemistry

Oxygen or nitrogen? Radical chemists overwhelmingly choose to work with xanthates rather than dithiocarbamates, yet the latter offer a distinct advantage in the case of a new method for generating carbamoyl radicals. Functionalized lactams of various ring sizes can be prepared in an operationally simple procedure involving irradiation or heating in the presence of a radical initiator (see scheme).

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