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Fluorescent Probes for Hydrogen Peroxide Based on a Non‐Oxidative Mechanism
Author(s) -
Maeda Hatsuo,
Fukuyasu Yuka,
Yoshida Shoko,
Fukuda Masako,
Saeki Kanako,
Matsuno Hiromi,
Yamauchi Yuji,
Yoshida Kenji,
Hirata Kazumasa,
Miyamoto Kazuhisa
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200452381
Subject(s) - hydrogen peroxide , fluorescence , oxidative phosphorylation , mechanism (biology) , chemistry , intracellular , fluorescein , combinatorial chemistry , biochemistry , biophysics , biology , physics , philosophy , epistemology , optics
Highly selective detection of H 2 O 2 through a non‐oxidative mechanism has been achieved by desulfonylation of 1 to the corresponding fluorescein. This approach has been used for the intracellular formation of H 2 O 2 in algal cells by using the acetyl derivatives of 1 as fluorescent probes.