Cover Picture: An Unusual Dynamic Fe‐Hg‐Pd Cluster with a Palladium( 0 ) Fragment Stabilized by d 10 –d 10  Heterometallic Bonding (Angew. Chem. Int. Ed. 19/2003) | Zendy

Schuh Walter | Zendy; Braunstein Pierre | Zendy; Bénard Marc | Zendy; Rohmer MarieMadeleine | Zendy; Welter Richard | Zendy

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Cover Picture: An Unusual Dynamic Fe‐Hg‐Pd Cluster with a Palladium( 0 ) Fragment Stabilized by d 10 –d 10 Heterometallic Bonding (Angew. Chem. Int. Ed. 19/2003)

Author(s) -

Schuh Walter,

Braunstein Pierre,

Bénard Marc,

Rohmer MarieMadeleine,

Welter Richard

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390450

Subject(s) - palladium , cover (algebra) , cluster (spacecraft) , fragment (logic) , crystallography , metal , chemistry , center (category theory) , stereochemistry , materials science , catalysis , organic chemistry , computer science , engineering , mechanical engineering , programming language

What goes around comes around. The cover picture describes how a Pd center undergoes an oscillating motion along the Fe‐Hg‐Fe metal chain of a cluster that exhibits helically arranged diphenylphosphanylmethane ligands. The Pd 0 fragment was “captured” by a trimetallaphosphane that can easily adapt its conformation through rotation about a HgFe bond. For more details of this unusual cluster, which exhibits an unprecedented PdHg d 10 –d 10 interaction, see the Communication by P. Braunstein et al. on page 2161ff.

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