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Dynamic Materials through Metal‐Directed and Solvent‐Driven Self‐Assembly of Cavitands
Author(s) -
Pirondini Laura,
Stendardo Anna G.,
Geremia Silvano,
Campagnolo Mara,
Samorì Paolo,
Rabe Jürgen P.,
Fokkens Roel,
Dalcanale Enrico
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200390355
Subject(s) - solvophobic , supramolecular chemistry , self assembly , nanotechnology , dual (grammatical number) , metal , solvent , chemistry , materials science , computer science , organic chemistry , molecule , art , literature
A dual‐coded dynamic material was created by the bimodal self‐assembly protocol sketched in the scheme. The combination of two orthogonal and reversible interactions, namely solvophobic aggregation (SA) and metal coordination (MC), allows precise control at each step of the self‐assembly cycle, leading to the formation of rodlike supramolecular architectures.