Synthesis of a Chiral Tube | Zendy

Herges Rainer | Zendy; Deichmann Markus | Zendy; Wakita Tsuneki | Zendy; Okamoto Yoshio | Zendy

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Synthesis of a Chiral Tube

Author(s) -

Herges Rainer,

Deichmann Markus,

Wakita Tsuneki,

Okamoto Yoshio

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390308

Subject(s) - enantiomer , tube (container) , alkylation , phase (matter) , carbon nanotube , carbon fibers , chiral stationary phase , chirality (physics) , materials science , conjugated system , chemistry , organic chemistry , nanotechnology , catalysis , polymer , chiral symmetry , composite material , physics , composite number , particle physics , quark , nambu–jona lasinio model

“Picotubes” : A chiral tube is formed in the surprisingly clean Friedel–Crafts alkylation of a fully conjugated tubelike structure. Unlike helical carbon nanotubes synthesized at high temperatures, this chemically modified picotube is chiral by substitution. The two enantiomers were separated by chromatography on a chiral stationary phase.

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