Topomerization of a Distorted Diamond‐Shaped Tetraborane(4) and Its Hydroboration to a  closo ‐Pentaborane(7) with a  nido  Structure | Zendy

Präsang Carsten | Zendy; Hofmann Matthias | Zendy; Geiseler Gertraud | Zendy; Massa Werner | Zendy; Berndt Armin | Zendy

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Topomerization of a Distorted Diamond‐Shaped Tetraborane(4) and Its Hydroboration to a closo ‐Pentaborane(7) with a nido Structure

Author(s) -

Präsang Carsten,

Hofmann Matthias,

Geiseler Gertraud,

Massa Werner,

Berndt Armin

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390271

Subject(s) - boranes , diamond , hydroboration , isomerization , chemistry , derivative (finance) , diagonal , borane , stereochemistry , organic chemistry , boron , geometry , catalysis , mathematics , financial economics , economics

The exchange of the short and long diagonal of the B 4 diamond of 1 is the simplest variant to date of the diamond–square–diamond rearrangement, which plays a central role in the isomerization of polyhedral boranes, carboranes, and metallaboranes. Compound 2 , which is readily accessible from 1 , is the first derivative of pentaborane(7).

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