Synthesis and Structure of Cyclic Gold( I ) Phosphanyl Complexes [{Au(PR 2 )}  n  ] | Zendy

Stefanescu Diana M. | Zendy; Yuen Holming F. | Zendy; Glueck David S. | Zendy; Golen James A. | Zendy; Rheingold Arnold L. | Zendy

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Synthesis and Structure of Cyclic Gold( I ) Phosphanyl Complexes [{Au(PR 2 )} n ]

Author(s) -

Stefanescu Diana M.,

Yuen Holming F.,

Glueck David S.,

Golen James A.,

Rheingold Arnold L.

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390270

Subject(s) - solid state , chemistry , content (measure theory) , crystallography , computer science , nanotechnology , stereochemistry , materials science , mathematics , mathematical analysis

Gold(I) Phosphanyl Complexes , such as [Au(PR 2 )] n , have been known for more than 25 years. However, the solid‐state structure of such complexes, as well as their nature in solution, has remained somewhat of a mystery. The figure displays the cyclic and polymeric forms that are possible (L=endgroup). The structures of the complexes, and the occurrence of Au⋅⋅⋅Au interactions are discussed.

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