Molecular Mousetraps: Gas‐Phase Studies of the Covalent Coupling of Noncovalent Complexes Initiated by Reactive Carbenes Formed by Controlled Activation of Diazo Precursors | Zendy

Julian Ryan R. | Zendy; May Jeremy A. | Zendy; Stoltz Brian M. | Zendy; Beauchamp J. L. | Zendy

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Molecular Mousetraps: Gas‐Phase Studies of the Covalent Coupling of Noncovalent Complexes Initiated by Reactive Carbenes Formed by Controlled Activation of Diazo Precursors

Author(s) -

Julian Ryan R.,

May Jeremy A.,

Stoltz Brian M.,

Beauchamp J. L.

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390258

Subject(s) - diazo , carbene , dissociation (chemistry) , chemistry , covalent bond , reactive intermediate , non covalent interactions , intermolecular force , gas phase , molecule , photochemistry , polymer chemistry , computational chemistry , organic chemistry , catalysis , hydrogen bond

The covalent linking of noncovalently bound host–guest complexes in the gas phase is achieved by the formation of a highly reactive carbene from the host molecule, which is generated by collision‐activated dissociation. Possible mechanisms for the resulting intermolecular reactions are explored by theory and experiment.

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