Premium
Intercalation of Alkali Metal Cations into Layered Organotitanium Oxides
Author(s) -
Gracia José,
Martín Avelino,
Mena Miguel,
MoralesVarela María del Carmen,
Poblet JosepM.,
Santamaría Cristina
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200390246
Subject(s) - alkali metal , deprotonation , intercalation (chemistry) , amide , inorganic chemistry , chemistry , reagent , alkyl , metal , titanium , polymer chemistry , ion , organic chemistry
Deprotonation of the complex [{Ti(η 5 ‐C 5 Me 5 )(μ‐O)} 3 (μ 3 ‐CH)] with different alkali metal alkyl and amide reagents provides a method for the intercalation of alkali‐metal ions into layered organometallic titanium oxides (see picture). The process and the structures were analyzed by DFT calculations.