[Ge 8 {N(SiMe 3 ) 2 } 6 ]: A Ligand‐Stabilized Ge Cluster Compound with Formally Zero‐Valent Ge Atoms | Zendy

Schnepf Andreas | Zendy; Köppe Ralf | Zendy

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[Ge 8 {N(SiMe 3 ) 2 } 6 ]: A Ligand‐Stabilized Ge Cluster Compound with Formally Zero‐Valent Ge Atoms

Author(s) -

Schnepf Andreas,

Köppe Ralf

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390241

Subject(s) - germanium , cluster (spacecraft) , crystallography , germanium compounds , bromide , condensation , oxidation state , ligand (biochemistry) , chemistry , materials science , physics , inorganic chemistry , silicon , metal , biochemistry , receptor , organic chemistry , computer science , thermodynamics , programming language

Starting from germanium( I ) bromide , which can be obtained by preparative co‐condensation, the first polyhedral Ge cluster [Ge 8 {N(SiMe 3 ) 2 } 6 ] (see picture) has been synthesized in which the average oxidation state of all the Ge atoms in the cluster core lies between 0 and +1.

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