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The First Thorium Arene Complex: A Divalent Synthon
Author(s) -
Korobkov Ilia,
Gambarotta Sandro,
Yap Glenn P. A.
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200390217
Subject(s) - synthon , thorium , divalent , chemistry , stereochemistry , materials science , organic chemistry , uranium , metallurgy
A highly reactive thorium naphthalene complex , namely 1 ‐[Li(dme) 3 ] was prepared by reducing a Th IV precursor with Li(naphthalene). The complex behaves as a synthon for Th II and reacts with Me 3 SiN 3 to give the thorium silazanate 2 .
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