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Reactions of Triazacyclohexanes with CuCl 2 : Surprising Formation of a Dimer between Two [CuCl 2 ] − Ions with an Unsupported Cuprophilic Attraction
Author(s) -
Köhn Randolf D.,
Seifert Guido,
Pan Zhida,
Mahon Mary F.,
KociokKöhn Gabriele
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200390210
Subject(s) - dimer , octahedron , ion , attraction , chemistry , copper , crystallography , organic chemistry , philosophy , linguistics
Cuprophilic interactions are observed between the two copper centers of the unprecedented dimer 2 , the structure of which contains two associated [Cu I Cl 2 ] − ions. The surrounding complex is derived from the internal reduction of the Cu II complex 1 , which displays a cis ‐divacant octahedral coordination geometry.
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