Single Crystals of the Disubstituted Anthracene 9,10‐(Ph 2 PS) 2 C 14 H 8  Selectively and Reversibly Detect Toluene by Solid‐State Fluorescence Emission | Zendy

Fei Zhaofu | Zendy; Kocher Nikolaus | Zendy; Mohrschladt Christian J. | Zendy; Ihmels Heiko | Zendy; Stalke Dietmar | Zendy

Premium

Single Crystals of the Disubstituted Anthracene 9,10‐(Ph 2 PS) 2 C 14 H 8 Selectively and Reversibly Detect Toluene by Solid‐State Fluorescence Emission

Author(s) -

Fei Zhaofu,

Kocher Nikolaus,

Mohrschladt Christian J.,

Ihmels Heiko,

Stalke Dietmar

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390207

Subject(s) - toluene , chromophore , anthracene , benzene , stacking , excimer , molecule , fluorescence , chemistry , crystallography , pyrene , photochemistry , physics , organic chemistry , optics

Not π stacking but CH⋅⋅⋅π‐ring center interactions lead to the fluorescence emission observed for the first time from a heteromolecular excimer complex. In single crystals a toluene molecule is located perpendicular to a Ph 2 P(S)‐disubstituted anthracene chromophore. This toluene complex fluoresces (see picture) but the benzene complex does not.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research