A Diboracyclopropane with a Planar‐Tetracoordinate Carbon Atom and a Triborabicyclobutane | Zendy

Sahin Yüksel | Zendy; Präsang Carsten | Zendy; Hofmann Matthias | Zendy; Subramanian Govindan | Zendy; Geiseler Gertraud | Zendy; Massa Werner | Zendy; Berndt Armin | Zendy

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A Diboracyclopropane with a Planar‐Tetracoordinate Carbon Atom and a Triborabicyclobutane

Author(s) -

Sahin Yüksel,

Präsang Carsten,

Hofmann Matthias,

Subramanian Govindan,

Geiseler Gertraud,

Massa Werner,

Berndt Armin

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390185

Subject(s) - tetracoordinate , carbon atom , atom (system on chip) , tetrahedron , planar , carbon fibers , ring (chemistry) , crystallography , chemistry , materials science , organic chemistry , computer science , computer graphics (images) , composite number , composite material , embedded system

Four‐coordinate in a three‐membered ring and thereby planar : The chemical shift of the skeletal carbon atom of 1 , which was generated and spectroscopically characterized at −90 °C, agrees very well with that computed for the model 2 , but differs by 70 ppm from that of the similarly substituted, but distorted‐tetrahedral carbon atom in 3 . R=SiMe 3 , Dur=2,3,5,6‐tetramethylphenyl.

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