Coordinated  o ‐Dithio‐ and  o ‐Iminothiobenzosemiquinonate(1−) π Radicals in [M II (bpy)(L . )](PF 6 ) Complexes | Zendy

Ghosh Prasanta | Zendy; Begum Ameerunisha | Zendy; Herebian Diran | Zendy; Bothe Eberhard | Zendy; Hildenbrand Knut | Zendy; Weyhermüller Thomas | Zendy; Wieghardt Karl | Zendy

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Coordinated o ‐Dithio‐ and o ‐Iminothiobenzosemiquinonate(1−) π Radicals in [M II (bpy)(L . )](PF 6 ) Complexes

Author(s) -

Ghosh Prasanta,

Begum Ameerunisha,

Herebian Diran,

Bothe Eberhard,

Hildenbrand Knut,

Weyhermüller Thomas,

Wieghardt Karl

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390162

Subject(s) - radical , palladium , chemistry , platinum , electron paramagnetic resonance , ion , crystallography , paramagnetism , ligand (biochemistry) , bipyridine , crystal structure , nuclear magnetic resonance , physics , catalysis , biochemistry , receptor , organic chemistry , quantum mechanics

Reversible ligand‐centered one‐electron oxidation of square‐planar neutral complexes of palladium( II ) and platinum( II ) [M(bpy)(L)] (bpy=bipyridine, L: see picture) leads to the paramagnetic complexes [M(bpy)(L . )] + . Thus, the existence of S,S‐coordinated o ‐dithiobenzosemiquinonate(1−) π radical ions has been proven unequivocally.

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