Nitrido Ruthenium Porphyrins: Synthesis, Characterization, and Amination Reactions with Hydrocarbon or Silyl Enol Ethers | Zendy

Leung Sarana KaYan | Zendy; Huang JieSheng | Zendy; Liang JiangLin | Zendy; Che ChiMing | Zendy; Zhou ZhongYuan | Zendy

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Nitrido Ruthenium Porphyrins: Synthesis, Characterization, and Amination Reactions with Hydrocarbon or Silyl Enol Ethers

Author(s) -

Leung Sarana KaYan,

Huang JieSheng,

Liang JiangLin,

Che ChiMing,

Zhou ZhongYuan

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390111

Subject(s) - ruthenium , silylation , chemistry , enol , amination , trifluoroacetic anhydride , yield (engineering) , organic chemistry , porphyrin , catalysis , materials science , metallurgy

An unprecedented synthetic strategy was used for the preparation of nitrido ruthenium( VI ) porphyrins such as 1 . The structure of 1 features a RuN (nitrido) distance of 1.656(5) Å. Reactions of nitrido ruthenium( VI ) porphyrins with silyl enol ethers or indan, in the presence of trifluoroacetic anhydride, afforded N ‐trifluoroacetyl amines in up to 84 % yield.

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