Open Network Architectures from the Self‐Assembly of AgNO 3  and 5,10,15,20‐Tetra(4‐pyridyl)porphyrin (H 2 tpyp) Building Blocks: The Exceptional Self‐Penetrating Topology of the 3D Network of [Ag 8 (Zn II tpyp) 7 (H 2 O) 2 ](NO 3 ) 8 | Zendy

Carlucci Lucia | Zendy; Ciani Gianfranco | Zendy; Proserpio Davide M. | Zendy; Porta Francesca | Zendy

Premium

Open Network Architectures from the Self‐Assembly of AgNO 3 and 5,10,15,20‐Tetra(4‐pyridyl)porphyrin (H 2 tpyp) Building Blocks: The Exceptional Self‐Penetrating Topology of the 3D Network of [Ag 8 (Zn II tpyp) 7 (H 2 O) 2 ](NO 3 ) 8

Author(s) -

Carlucci Lucia,

Ciani Gianfranco,

Proserpio Davide M.,

Porta Francesca

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390106

Subject(s) - tetra , porphyrin , self assembly , topology (electrical circuits) , materials science , nanotechnology , chemistry , computer science , mathematics , combinatorics , organic chemistry , medicinal chemistry

Very large free voids (more than 50 % of the cell volume) and interesting stuctural motifs are found in the 2D and 3D frameworks assembled using AgNO 3 and 5,10,15,20‐tetra(4‐pyridyl)porphyrin (H 2 tpyp) building blocks. The robust 3D network of [Ag 8 (Zn II tpyp) 7 (H 2 O) 2 ](NO 3 ) 8 is particularly fascinating in that it exhibits a unique self‐penetrating topology (see figure) and can be reversibly desolvated.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research