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Macrocycle Synthesis by Olefin Metathesis on a Nanosized, Shape‐Persistent Tricationic Platinum Template
Author(s) -
Chuchuryukin Aleksey V.,
Dijkstra Harm P.,
Suijkerbuijk Bart M. J. M.,
Klein Gebbink Robertus J. M.,
van Klink Gerard P. M.,
Mills Allison M.,
Spek Anthony L.,
van Koten Gerard
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200390086
Subject(s) - pincer movement , olefin metathesis , tris , benzene , metathesis , combinatorial chemistry , non blocking i/o , chemistry , information retrieval , computer science , organic chemistry , catalysis , polymerization , biochemistry , polymer
A 69‐membered ring (see picture) results from a metathesis reaction that uses a metalated tris(pincer)‐substituted benzene as scaffold. The macrocyclic product can be detached by the addition of Cl − after which the template is recovered quantitatively.