High‐Spin Wheel of a Heptanuclear Mixed‐Valent Fe II,III  Complex | Zendy

Oshio Hiroki | Zendy; Hoshino Norihisa | Zendy; Ito Tasuku | Zendy; Nakano Motohiro | Zendy; Renz Franz | Zendy; Gütlich Philipp | Zendy

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High‐Spin Wheel of a Heptanuclear Mixed‐Valent Fe II,III Complex

Author(s) -

Oshio Hiroki,

Hoshino Norihisa,

Ito Tasuku,

Nakano Motohiro,

Renz Franz,

Gütlich Philipp

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390084

Subject(s) - spins , schiff base , ligand (biochemistry) , spin states , spin (aerodynamics) , chemistry , ground state , oxidation state , crystallography , chloride , inorganic chemistry , physics , catalysis , atomic physics , condensed matter physics , organic chemistry , thermodynamics , biochemistry , receptor

Wheels with high spins: The reaction of a tridentate Schiff base ligand with iron( II ) chloride, and subsequent oxidation with [( t Bu 4 N)MnO 4 ] yielded a heptanuclear mixed‐valent iron wheel (see picture) with a spin ground state of S =29/2.

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