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[(η 5 ‐C 5 H 5 )(OC) 3 VBN(SiMe 3 ) 2 : A Half‐Sandwich Complex with a Terminal Borylene Ligand
Author(s) -
Braunschweig Holger,
Colling Miriam,
Hu Chunhua,
Radacki Krzysztof
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200390079
Subject(s) - intermetallic , vanadium , boron , crystallography , chemistry , terminal (telecommunication) , physics , materials science , stereochemistry , inorganic chemistry , metallurgy , nuclear physics , alloy , telecommunications , computer science
A vanadium–boron distance of 1.971 Å characterizes the first classical bond between these two elements. The novel half‐sandwich complex 1 was obtained from [(OC) 5 CrBN(SiMe 3 ) 2 ] by photochemically induced intermetallic borylene transfer.