Premium
[(η 5 ‐C 5 H 5 )(OC) 3 VBN(SiMe 3 ) 2 : A Half‐Sandwich Complex with a Terminal Borylene Ligand
Author(s) -
Braunschweig Holger,
Colling Miriam,
Hu Chunhua,
Radacki Krzysztof
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200390079
Subject(s) - intermetallic , vanadium , boron , crystallography , chemistry , terminal (telecommunication) , physics , materials science , stereochemistry , inorganic chemistry , metallurgy , nuclear physics , alloy , telecommunications , computer science
A vanadium–boron distance of 1.971 Å characterizes the first classical bond between these two elements. The novel half‐sandwich complex 1 was obtained from [(OC) 5 CrBN(SiMe 3 ) 2 ] by photochemically induced intermetallic borylene transfer.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom