Perfluorinated  meso ‐Aryl‐Substituted Expanded Porphyrins | Zendy

Shimizu Soji | Zendy; Shin JiYoung | Zendy; Furuta Hiroyuki | Zendy; Ismael Rami | Zendy; Osuka Atsuhiro | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Perfluorinated meso ‐Aryl‐Substituted Expanded Porphyrins

Author(s) -

Shimizu Soji,

Shin JiYoung,

Furuta Hiroyuki,

Ismael Rami,

Osuka Atsuhiro

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390058

Subject(s) - alternation (linguistics) , aryl , planar , crystallography , chemistry , materials science , stereochemistry , computer science , organic chemistry , philosophy , computer graphics (images) , linguistics , alkyl

Twisted figure‐of‐eight structures are found for the perfluorinated meso ‐aryl‐substituted expanded porphyrins synthesized from 3,4‐difluoropyrrole and pentafluorobenzaldehyde under modified Rothemund–Lindsey conditions. The crystal structure of the [26]hexaphyrin (see picture) consists of two almost planar tripyrrolic subunits which are tilted by approximately 60° in which a distinct alternation in the bond lengths of the π‐electronic system is evident.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research