Reversible Formation of Iodosylbenzene–Iron Porphyrin Intermediates in the Reaction of Oxoiron( IV ) Porphyrin π‐Cation Radicals and Iodobenzene | Zendy

Nam Wonwoo | Zendy; Choi Sun Kyung | Zendy; Lim Mi Hee | Zendy; Rohde JanUwe | Zendy; Kim Inwoo | Zendy; Kim Jinheung | Zendy; Kim Cheal | Zendy; Que, Jr. Lawrence | Zendy

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Reversible Formation of Iodosylbenzene–Iron Porphyrin Intermediates in the Reaction of Oxoiron( IV ) Porphyrin π‐Cation Radicals and Iodobenzene

Author(s) -

Nam Wonwoo,

Choi Sun Kyung,

Lim Mi Hee,

Rohde JanUwe,

Kim Inwoo,

Kim Jinheung,

Kim Cheal,

Que, Jr. Lawrence

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200390036

Subject(s) - porphyrin , iodobenzene , chemistry , radical , photochemistry , epoxide , medicinal chemistry , catalysis , organic chemistry

The electronic nature of iron porphyrin complexes and iodobenzene derivatives markedly influences the formation of iodosylbenzene–iron( III ) porphyrin intermediates 2 , which are generated in the reaction of oxoiron( IV ) porphyrin cation radicals 1 and iodobenzene. Epoxidation of olefins by 2 affords high yields of epoxide products.

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