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Reversible Formation of Iodosylbenzene–Iron Porphyrin Intermediates in the Reaction of Oxoiron( IV ) Porphyrin π‐Cation Radicals and Iodobenzene
Author(s) -
Nam Wonwoo,
Choi Sun Kyung,
Lim Mi Hee,
Rohde JanUwe,
Kim Inwoo,
Kim Jinheung,
Kim Cheal,
Que, Jr. Lawrence
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200390036
Subject(s) - porphyrin , iodobenzene , chemistry , radical , photochemistry , epoxide , medicinal chemistry , catalysis , organic chemistry
The electronic nature of iron porphyrin complexes and iodobenzene derivatives markedly influences the formation of iodosylbenzene–iron( III ) porphyrin intermediates 2 , which are generated in the reaction of oxoiron( IV ) porphyrin cation radicals 1 and iodobenzene. Epoxidation of olefins by 2 affords high yields of epoxide products.