Nickel‐Catalyzed Tandem Carbostannylation of Alkynes and 1,2‐Dienes with Alkynylstannanes | Zendy

Shirakawa Eiji | Zendy; Yamamoto Youko | Zendy; Nakao Yoshiaki | Zendy; Oda Shinichi | Zendy; Tsuchimoto Teruhisa | Zendy; Hiyama Tamejiro | Zendy

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Nickel‐Catalyzed Tandem Carbostannylation of Alkynes and 1,2‐Dienes with Alkynylstannanes

Author(s) -

Shirakawa Eiji,

Yamamoto Youko,

Nakao Yoshiaki,

Oda Shinichi,

Tsuchimoto Teruhisa,

Hiyama Tamejiro

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200353649

Subject(s) - tandem , catalysis , nickel , chemistry , carbon fibers , transition metal , tin , polymer chemistry , combinatorial chemistry , organic chemistry , materials science , composite number , composite material

Alkynes and 1,2‐dienes insert into the carbon–tin bond of alkynylstannanes to afford various stannyldienynes in the presence of a nickel catalyst (see scheme). This is the first example of a transition‐metal‐catalyzed tandem carbometalation of two different carbon–carbon unsaturated bonds.

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