Premium
Intramolecular CH Activation in Complexes with MoBi Metal Bonds
Author(s) -
Roggan Stefan,
Limberg Christian,
Ziemer Burkhard,
Brandt Marcus
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200353576
Subject(s) - intramolecular force , chemistry , metal , bond , alcohol , stereochemistry , organic chemistry , business , finance
“ Banana bonds ” between Bi and C are a feature of 2 , which forms in the course of intramolecular alcohol eliminations from 1 . CH activations through complex‐induced proximity effects are responsible for these unexpected eliminations.