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Solution Structure and Reagent Binding of the Zinc Alkoxide Catalyst in the Soai Asymmetric Autocatalytic Reaction
Author(s) -
Gridnev Ilya D.,
Serafimov Jörg M.,
Brown John M.
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200353572
Subject(s) - autocatalysis , alkoxide , chemistry , reagent , catalysis , zinc , nuclear magnetic resonance spectroscopy , computational chemistry , crystallography , inorganic chemistry , stereochemistry , organic chemistry
All square : A {ZnO} 2 square resting state in autocatalysis is revealed by NMR spectroscopy and endorsed by DFT calculations (see picture). Its dynamic behavior and reversible binding of excess i Pr 2 Zn are defined.
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