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Nanoporous Metal‐Containing Nickel Phosphates: A Class of Shape‐Selective Catalyst
Author(s) -
Chang JongSan,
Hwang JinSoo,
Jhung Sung Hwa,
Park SangEon,
Férey Gérard,
Cheetham Anthony K.
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200353502
Subject(s) - nanoporous , catalysis , nickel , selectivity , metal , ion exchange , inorganic chemistry , photocatalysis , chemistry , redox , phosphate , materials science , ion , organic chemistry
A substitute for zeolites : The nanoporous nickel phosphate VSB‐1 exhibits zeolitic properties and very weak acidity and basicity (see picture). When VSB‐1 is modified by metal‐ion exchange or through metal incorporation into the framework, it offers promising catalytic properties, such as shape selectivity, and activity in both redox catalysis and photocatalysis.