Assembling Dimeric π Stacks on Gold Surfaces by Using Three‐Dimensional Lock‐and‐Key Receptors | Zendy

Tulevski George S. | Zendy; Bushey Mark L. | Zendy; Kosky Jenna L. | Zendy; Ruter Shane J. T. | Zendy; Nuckolls Colin | Zendy

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Assembling Dimeric π Stacks on Gold Surfaces by Using Three‐Dimensional Lock‐and‐Key Receptors

Author(s) -

Tulevski George S.,

Bushey Mark L.,

Kosky Jenna L.,

Ruter Shane J. T.,

Nuckolls Colin

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200353476

Subject(s) - substituent , hydrogen bond , chemistry , lock (firearm) , receptor , crystallography , nanotechnology , stereochemistry , molecule , materials science , organic chemistry , biochemistry , mechanical engineering , engineering

Nest building : a method to create a rigid hydrogen‐bond receptor through the simultaneous binding of three thiol substituent groups to a gold surface is reported (see picture: red=O, gray=C, blue=N, yellow=S, purple=Au surface atom). These receptors are able to distinguish and select for π surfaces with a complementary size, shape, and hydrogen‐bonding code.

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