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Reaction‐Temperature‐Dependent Supramolecular Isomerism of Coordination Networks Based on the Organometallic Building Block [Cu I 2 (μ 2 ‐BQ)(μ 2 ‐OAc) 2 ]
Author(s) -
Masaoka Shigeyuki,
Tanaka Daisuke,
Nakanishi Yasunori,
Kitagawa Susumu
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200353463
Subject(s) - synthon , supramolecular chemistry , chemistry , block (permutation group theory) , solvent , phase (matter) , group 2 organometallic chemistry , content (measure theory) , crystallography , stereochemistry , molecule , crystal structure , organic chemistry , combinatorics , mathematics , mathematical analysis
Three supramolecular isomers , [Cu ${{{{\rm {\rm I}}\hfill \atop 2\hfill}}}$ (μ 4 ‐BQ)(μ 2 ‐OAc) 2 ] n (α phase), [Cu ${{{{\rm {\rm I}}\hfill \atop 2\hfill}}}$ (μ 3 ‐BQ)(μ 2 ‐OAc)(μ 3 ‐OAc)] n (β phase), and [Cu ${{{{\rm {\rm I}}\hfill \atop 2\hfill}}}$ (μ 2 ‐BQ)(μ 3 ‐OAc) 2 ] n (γ phase), were crystallized by using the organometallic building block shown, which has two types of supramolecular synthon. Interestingly, these three supramolecular isomers were crystallized from the same solvent. BQ=benzoquinone.