Li–Cu Exchange in Intercalated Cu 3 N—With a Remark on Cu 4 N | Zendy

Gulo Fakhili | Zendy; Simon Arndt | Zendy; Köhler Jürgen | Zendy; Kremer Reinhard K. | Zendy

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Li–Cu Exchange in Intercalated Cu 3 N—With a Remark on Cu 4 N

Author(s) -

Gulo Fakhili,

Simon Arndt,

Köhler Jürgen,

Kremer Reinhard K.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200353424

Subject(s) - intercalation (chemistry) , crystallography , ion , substitution (logic) , chemistry , ion exchange , inorganic chemistry , materials science , organic chemistry , computer science , programming language

A surprising substitution of Cu by Li has been observed during the intercalation reaction of Cu 3 N with n ‐butyllithium, besides an expected incorporation of Li. The twofold coordinated Cu + ions are shifted into cuboctahedral cavities along with a reduction to Cu 0 (see picture). The chemical bonding of the compounds Li x Cu 3 N is analyzed in comparison to Cu 4 N on the basis of band‐structure calculations.

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