Premium
A Water‐Soluble Tetranuclear Zr IV Compound Supported by the Kläui Tripodal Ligand: A Model of Zr IV in Aqueous Media
Author(s) -
Zhang QianFeng,
Lam Tony C. H.,
Chan Eddie Y. Y.,
Lo Samuel M. F.,
Williams Ian D.,
Leung WaHung
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200353298
Subject(s) - ligand (biochemistry) , aqueous medium , aqueous solution , chemistry , zirconium , medicinal chemistry , crystallography , stereochemistry , nuclear chemistry , inorganic chemistry , receptor , biochemistry
Water soluble and stable : The treatment of zirconyl nitrate with the Kläui tripodal oxygen ligand in dilute nitric acid gives a water‐soluble tetranuclear hydroxo‐bridged Zr IV compound (depicted, C gray; O red; P purple; Co blue; Zr green), which reacts with a phosphodiester to give a Zr IV phosphate cubane cluster.