A Water‐Soluble Tetranuclear Zr IV  Compound Supported by the Kläui Tripodal Ligand: A Model of Zr IV  in Aqueous Media | Zendy

Zhang QianFeng | Zendy; Lam Tony C. H. | Zendy; Chan Eddie Y. Y. | Zendy; Lo Samuel M. F. | Zendy; Williams Ian D. | Zendy; Leung WaHung | Zendy

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A Water‐Soluble Tetranuclear Zr IV Compound Supported by the Kläui Tripodal Ligand: A Model of Zr IV in Aqueous Media

Author(s) -

Zhang QianFeng,

Lam Tony C. H.,

Chan Eddie Y. Y.,

Lo Samuel M. F.,

Williams Ian D.,

Leung WaHung

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200353298

Subject(s) - ligand (biochemistry) , aqueous medium , aqueous solution , chemistry , zirconium , medicinal chemistry , crystallography , stereochemistry , nuclear chemistry , inorganic chemistry , receptor , biochemistry

Water soluble and stable : The treatment of zirconyl nitrate with the Kläui tripodal oxygen ligand in dilute nitric acid gives a water‐soluble tetranuclear hydroxo‐bridged Zr IV compound (depicted, C gray; O red; P purple; Co blue; Zr green), which reacts with a phosphodiester to give a Zr IV phosphate cubane cluster.

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