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Theoretical Search for Very Short Metal–Actinide Bonds: NUIr and Isoelectronic Systems
Author(s) -
Gagliardi Laura,
Pyykkö Pekka
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200353261
Subject(s) - triple bond , actinide , bond , chemistry , molecule , chemical bond , metal , atom (system on chip) , series (stratigraphy) , bond energy , computational chemistry , inorganic chemistry , double bond , organic chemistry , computer science , finance , economics , embedded system , paleontology , biology
Cumulated triple bonds : A new class of molecules, the isoelectronic series of NUIr, (depicted) has been postulated and theoretically studied. The bond between the actinide and the 5d‐metal atom is very short and is shown to correspond to triple bonding. The NU bond is also a triple bond.