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Shuttling through Anion Recognition
Author(s) -
Keaveney Claire M.,
Leigh David A
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200353248
Subject(s) - ion , polar , chromosomal translocation , chemistry , content (measure theory) , computer science , combinatorial chemistry , biochemistry , physics , organic chemistry , mathematics , mathematical analysis , astronomy , gene
A negative response : Anion formation induces translocation of the macrocycle in a molecular shuttle (see picture). Shuttling only occurs in polar solvents and is unaffected by the nature of the countercation or the presence of other anions.