Observation and Dynamics of “Charge‐Transfer Isomers” | Zendy

Ito Tasuku | Zendy; Imai Naoyuki | Zendy; Yamaguchi Tadashi | Zendy; Hamaguchi Tomohiko | Zendy; Londergan Casey H. | Zendy; Kubiak Clifford P. | Zendy

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Observation and Dynamics of “Charge‐Transfer Isomers”

Author(s) -

Ito Tasuku,

Imai Naoyuki,

Yamaguchi Tadashi,

Hamaguchi Tomohiko,

Londergan Casey H.,

Kubiak Clifford P.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200353221

Subject(s) - charge (physics) , chemical physics , dynamics (music) , chemistry , molecular dynamics , computational chemistry , physics , quantum mechanics , acoustics

Upon electrochemical reduction , asymmetrically substituted dimers of Ru 3 clusters [Ru 3 O(OAc) 6 (L)(CO)(μ‐pz)Ru 3 O(OAc) 6 (L′)(CO)] (pz=pyrazine, L and L′ are N ligands), exhibit IR spectral line coalescence in the ν CO region. The IR spectra suggest the existence of two possible “charge‐transfer isomers” for example, [A − –B] and [A–B − ], in which A and B represent different Ru 3 moieties.

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