Cationic and Neutral Four‐Coordinate Alkylidene Complexes of Vanadium( IV ) Containing Short VC Bonds | Zendy

Basuli Falguni | Zendy; Kilgore Uriah J. | Zendy; Hu Xile | Zendy; Meyer Karsten | Zendy; Pink Maren | Zendy; Huffman John C. | Zendy; Mindiola Daniel J. | Zendy

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Cationic and Neutral Four‐Coordinate Alkylidene Complexes of Vanadium( IV ) Containing Short VC Bonds

Author(s) -

Basuli Falguni,

Kilgore Uriah J.,

Hu Xile,

Meyer Karsten,

Pink Maren,

Huffman John C.,

Mindiola Daniel J.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200353210

Subject(s) - cationic polymerization , vanadium , abstraction , chemistry , crystallography , medicinal chemistry , stereochemistry , inorganic chemistry , polymer chemistry , philosophy , epistemology

Kinetically stable , four‐coordinate vanadium( IV ) neopentylidene complexes such as [(Nacnac)VCH t Bu(thf)](BPh 4 ) (Nacnac − =[Ar]NC(Me)CHC(Me)N[Ar], Ar=2,6‐(CHMe 2 ) 2 C 6 H 3 ), which was prepared by oxidatively induced α‐hydrogen abstraction from [(Nacnac)V(CH 2 t Bu) 2 ] with AgBPh 4 in THF (see structure), contain the shortest VC bonds known to date.

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