A Tandem Semipinacol Rearrangement/Alkylation of α‐Epoxy Alcohols: An Efficient and Stereoselective Approach to Multifunctional 1,3‐Diols | Zendy

Hu XiangDong | Zendy; Fan ChunAn | Zendy; Zhang FuMin | Zendy; Tu Yong Qiang | Zendy

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A Tandem Semipinacol Rearrangement/Alkylation of α‐Epoxy Alcohols: An Efficient and Stereoselective Approach to Multifunctional 1,3‐Diols

Author(s) -

Hu XiangDong,

Fan ChunAn,

Zhang FuMin,

Tu Yong Qiang

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200353177

Subject(s) - stereocenter , tandem , stereoselectivity , alkylation , epoxy , carbon fibers , chemistry , scheme (mathematics) , stereochemistry , combinatorial chemistry , organic chemistry , computer science , catalysis , materials science , enantioselective synthesis , mathematics , algorithm , composite number , mathematical analysis , composite material

Three contiguous stereocenters , two of which are quaternary carbon atoms, were efficiently and stereoselectively constructed by a tandem semipinacol rearrangement/alkylation of α‐epoxy alcohols with RB(OH) 2 (see scheme).

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