A Nonanuclear Iron( II ) Single‐Molecule Magnet | Zendy

Boudalis Athanassios K. | Zendy; Donnadieu Bruno | Zendy; Nastopoulos Vassilios | Zendy; ClementeJuan Juan Modesto | Zendy; Mari Alain | Zendy; Sanakis Yiannis | Zendy; Tuchagues JeanPierre | Zendy; Perlepes Spyros P. | Zendy

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A Nonanuclear Iron( II ) Single‐Molecule Magnet

Author(s) -

Boudalis Athanassios K.,

Donnadieu Bruno,

Nastopoulos Vassilios,

ClementeJuan Juan Modesto,

Mari Alain,

Sanakis Yiannis,

Tuchagues JeanPierre,

Perlepes Spyros P.

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200353147

Subject(s) - magnet , superparamagnetism , ferromagnetism , single molecule magnet , anisotropy , chemical physics , molecule , molecular magnets , exchange interaction , ground state , magnetic anisotropy , materials science , condensed matter physics , spin (aerodynamics) , chemistry , nanotechnology , molecular physics , magnetization , atomic physics , physics , magnetic field , optics , organic chemistry , thermodynamics , quantum mechanics

Dressed up to the nines : A nonanuclear Fe II complex exhibiting rare μ 4 :η 1 azido bridges that induce ferromagnetic exchange interactions possesses a core with a very large ground‐state spin (probably S =14, see picture). The combination of a large S value and the magnetic anisotropy of iron( II ) centers endows this unique species with superparamagnetic behavior (SMM=single‐molecule magnet).

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