Premium
Luminescent 2D Macrocyclic Networks Based on Starburst Molecules: [{Ag(CF 3 SO 3 )} 1.5 (tdapb)] and [{Ag(NO 3 )} 3 (tdapb)]
Author(s) -
Seward Corey,
Jia WenLi,
Wang RuiYao,
Enright Gary D.,
Wang Suning
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200353126
Subject(s) - trifluoromethanesulfonate , luminescence , molecule , ligand (biochemistry) , honeycomb , salt (chemistry) , ion , chemistry , combinatorial chemistry , photochemistry , materials science , optoelectronics , organic chemistry , catalysis , biochemistry , receptor , composite material
The impact of the anion on the assembly of extended 2D structures has been demonstrated by two distinct luminescent 2D lattices. Shown here is the macrocyclic cloverleaf‐shaped cavity obtained from the reaction of a starburst ligand with Ag(NO 3 ). Use of the triflate salt instead results in a honeycomb‐shaped cavity.