A Three‐Dimensional Ferrimagnet Composed of Mixed‐Valence Mn 4  Clusters Linked by an {Mn[N(CN) 2 ] 6 } 4−  Unit | Zendy

Miyasaka Hitoshi | Zendy; Nakata Kazuya | Zendy; Sugiura Kenichi | Zendy; Yamashita Masahiro | Zendy; Clérac Rodolphe | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A Three‐Dimensional Ferrimagnet Composed of Mixed‐Valence Mn 4 Clusters Linked by an {Mn[N(CN) 2 ] 6 } 4− Unit

Author(s) -

Miyasaka Hitoshi,

Nakata Kazuya,

Sugiura Kenichi,

Yamashita Masahiro,

Clérac Rodolphe

Publication year - 2004

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200353093

Subject(s) - ferrimagnetism , crystallography , valence (chemistry) , dicyanamide , formula unit , covalent bond , paramagnetism , molecule , materials science , chemistry , condensed matter physics , physics , magnetization , magnetic field , crystal structure , biochemistry , ionic liquid , organic chemistry , quantum mechanics , catalysis

A ferrimagnet with a 3D molecular network (depicted) has been synthesized and characterized. The compound is composed of units of mixed‐valence Mn 4 clusters, a unit that is well known for its single‐molecule magnet properties, and Mn II paramagnetic units. Both building blocks are linked by a dicyanamide bridging ligand to form a covalently bonded three‐dimensional network. The compound becomes a ferrimagnet at 4.1 K that exhibits a spin‐flip phenomenon under the influence of a magnetic field.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research