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Combinatorial Catalysis with Bimetallic Complexes: Robust and Efficient Catalysts for Atom‐Transfer Radical Additions
Author(s) -
Quebatte Laurent,
Scopelliti Rosario,
Severin Kay
Publication year - 2004
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200353084
Subject(s) - bimetallic strip , ruthenium , catalysis , rhodium , chemistry , atom (system on chip) , combinatorial chemistry , fragment (logic) , polymer chemistry , photochemistry , organic chemistry , computer science , embedded system , programming language
A radical alternative? Two highly efficient catalysts for atom‐transfer radical additions were discovered in a parallel screening of bimetallic complexes. Both catalysts contain a rhodium‐centered fragment (blue), which is connected through three chloro bridges to a ruthenium‐centered fragment (red).